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TBR Acidity factors

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TBR breaks acidity factors into 2 categories: primary that are based on the characteristics of the atom connected to the proton in question (size, el-neg and hybridization) and secondary (rest of molecule effects: donation/withdrawal via reasonance, donation/withdrawal induction).

I assumed primary ones are called that because we are to consider them first before looking for "tie-breakers" in the secondaries.

I don't understand this problem on page 39 of TBR organic 1:


What is observed...

TBR Acidity factors

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