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Ka vs Km

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Both are measures of affinity.

I would like clarifications as to how they are different.

My understanding is the following:

Km: The concentration of substrate at which half of the active sites are full.

Smaller Km indicates a higher affinity because it means you need less substrate to reach half full due to them being attracted.


Ka: [ Substrate enzyme complex] / [Enzyme concentration]

So a higher Ka would indicate that for the same enzyme concentration, the enzyme would be more...

Ka vs Km

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